Mixed-valence compounds based on heterometallic-oxo-clusters containing Sb(<scp>iii</scp>,<scp>v</scp>): crystal structures and proton conduction - 黄小荥课题组 | LabXing

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Mixed-valence compounds based on heterometallic-oxo-clusters containing Sb(<scp>iii</scp>,<scp>v</scp>): crystal structures and proton conduction

2024

期刊 Dalton Transactions

作者 Wei‐Yang Wen · Wen Ma · Bing Hu · Hui-Ping Xiao · Tian-Yu Pan · Jia-Ting Liu · Hao-Wei Lin · Xin-Xiong Li · Xiao-Ying Huang

Isostructural mixed-valence compounds H9.2[Co(H2O)6]{M0.5(H2O)3.5{M’(H2O)4[SbVO6[Co4.2(H2O)5SbIII6(μ3-O)2(tta)6]]}}2·nH2O (M = Co, M’ = Co, n = 9 (1); M = Cd0.39/Co0.61, M’ = Cd0.24/Co0.76, n = 7 (2)) were synthesized. The proton conductivity of 2 is 1.42 × 10−3 S·cm−1 at 85 °C and 98% RH.

卷 53
期 3
页码 1156-1162
Royal Society of Chemistry (RSC)
ISSN: 1477-9226
DOI: 10.1039/d3dt03904h