2024.06.14 实验室论文在Polymers上发表。Yi Zhang, Haoran Zheng, Honggeng Ding, Khan Abdul Jabbar, Ling Gao * and Guowei Zhao *, Ceria Quantum Dot Filler-Modified Polymer Electrolytes for Three-Dimensional-Printed Sodium Solid-State Batteries. Polymers (Basel). 16, 1707 (2024).
2024.04.24 实验室论文在Materials上发表。Yi Zhang, Haoran Zheng, Jiale You, Hongyang Zhao,*, Abdul Jabbar Khan, Ling Gao,* and Guowei Zhao* , Chlorine-Rich Na6−xPS5−xCl1+x: A Promising Sodium Solid Electrolyte for All-Solid-State Sodium Batteries. Materials (Basel). 17, 1980 (2024).
2024.02.08 实验室与上海大学唐亚博士团队的论文在ACS Omega上发表。Wang, X., Xu, X., Li, Y., Chen, W., Zhao, G., Wang, H., et al. (2024). Effects of Sodium Vacancies and Concentrations in Na3SO4F Solid Electrolyte. ACS Omega. doi:10.1021/acsomega.3c09500.
2024.01.17 实验室论文在ACS Sustain. Chem. Eng. 上发表。Zhang, Y., Chen, C., Zhao, G., and Zhang, R. (2024). Ceria Heterostructure Suppresses Oxygen Release of Na-Ion Battery Cathode Materials. ACS Sustain. Chem. Eng. 12, 2729–2738. doi:10.1021/acssuschemeng.3c07220.
2023.11.20 实验室文章在 Inorg. Chem. Commun. 上发表。Khan, A. J., Gao, L., Sajjad, M., Khan, S., Mateen, A., Ghaffar, A., et al. (2024). Synthesis of heterostructured ZnO-CeO2 nanocomposite for supercapacitor applications. Inorg. Chem. Commun. 159, 111794. doi:10.1016/j.inoche.2023.111794.
2023.10.27 实验室综述文章在Chem. Rec.上发表。A.J. Khan, M. Sajjad, S. Khan, M. Khan, A. Mateen, S.S. Shah, N. Arshid, L. He, Z. Ma, L. Gao, G*. Zhao*, Telluride‐Based Materials: A Promising Route for High Performance Supercapacitors, Chem. Rec. e202300302 (2023). doi:10.1002/tcr.202300302.
2023.10.25 实验室科研文章在Inorg. Chem. Commun.上发表。A.J. Khan#, L. Gao#, M. Sajjad, S. Khan, A. Mateen, A. Ghaffar, I.A. Malik, X. Liao, G. Zhao*, Synthesis of heterostructured ZnO-CeO2 nanocomposite for supercapacitor applications, Inorg. Chem. Commun. 159 (2024) 111794. doi:10.1016/j.inoche.2023.111794.
2024.02.08 实验室与上海大学唐亚博士团队的论文在J. Phys. Chem. Lett.上发表。Li, Y., Wang, X., Wang, H., He, T., Ye, D., Zhao, H., et al. (2023). Unraveling the Dominance of Structural Vacancies in Sodium Ion Conductivity in Na3SO4F. J. Phys. Chem. Lett. 14, 6832–6839. doi:10.1021/acs.jpclett.3c01220.
2023.05.29 实验室综述文章在Batteries & Supercaps上发表。A. Jabbar Khan, A. Mateen, S. Khan, L. He, W. Wang, A. Numan, K.-Q. Peng, I. Ahmed Malik, I. Hussain, G. Zhao*, 3D Printed Micro‐Electrochemical Energy Storage Devices, Batteries & Supercaps, 2023. 6 (2023) 1–23. doi:10.1002/batt.202300190.
2023.03.01 祝贺高凌副教授为第一作者的Argrodite结构的硫化物系论文在Science China Technological Science上发表。Ling Gao1, Yulin Xie1, Yan Tong1, Miao Xu2, Jiale You1, Huiping Wei1, Xiangxiang Yu1, Siqi Xu1, Yi Zhang1, Yong Che3, Ya Tang4, Kota Suzuki5, Ryoji Kanno5, Guowei Zhao*, Lithium-site substituted Argyrodite-type Li6PS5I Solid Electrolytes with Enhanced Ionic Conduction for All-Solid-State Batteries, Science China Technological Science, 2023.
2022.08.21 祝贺高凌老师、钟蕃等同学卤化物系固体电解质文章在 ACS Appl. Energy Mater. 上发表。
Gao, L.; Zhong, F.; Tong, Y.; Zhang, S.; You, J.; Wei, H.; Yu, X.; Xu, S.; Zhao, G.*, High Formability Bromide Solid Electrolyte with Improved Ionic Conductivity for Bulk-Type All-Solid-State Lithium–Metal Batteries. ACS Appl. Energy Mater. 2022.
2022.08.01 祝贺赵国伟老师与东京工业大学菅野了次(Kanno Ryoji)教授研究组合作的工作在Chem. Mater.上发表。
Zhao, G.; Suzuki, K.; Okumura, T.; Takeuchi, T.; Hirayama, M.; Kanno, R. Extending the Frontiers of Lithium-Ion Conducting Oxides: Development of Multicomponent Materials with γ-Li3PO4-Type Structures. Chem. Mater. 2022, 34 (9), 3948–3959.
2021.11.16 上海大学＆黄冈师范ACS Appl. Energy Mater.：Li6PS5Cl固体电解质的硼氢化物取代效应
https://www.x-mol.com/groups/zhaohongbin/news/21066
高离子导电率的固体电解质是发展全固态电池的关键组成部分。硫化物无机固体电解质具有较高的离子电导率，其中立方型的硫银锗矿型Li6PS5X (X = Cl, Br, I)化合物一直是科学研究和工业关注的主要焦点。人们在改善Li6PS5X离子电导率方面做出了相当大的努力，但主要是通过阳离子（P位点）掺杂。与阳离子掺杂相比，在X（或S）位点上进行阴离子替代的研究是比较少的。
上海大学赵宏滨、唐亚、黄冈师范学院赵国伟等提出通过机械球磨法制备硼氢基团取代的锂-硫银锗矿固体电解质(Li6PS5Cl1-x(BH4)x)，并系统的研究了硼氢化物掺杂的锂-硫银锗矿的结构变化以及离子电导率行为。
XRD分析结果表明，当x≤0.3时，所制备的样品具有锂-硫银锗矿结构（立方体，空间群为F4̅3m）。相反，当x>0.3时，观察到Li2S-P2S5-LiCl-LiBH4的复合相（主要有Li2S和LiCl相）。通过计算得到的晶格常数可以直观的感受到硼氢基团引入后的变化，在x≤0.3时，晶格常数a随x的增大而增大，这也对应着BH4-（2.06 Å）取代Cl-（1.80 Å）所带来的晶格膨胀。
创建: May 31, 2023 | 13:57
