Aqueous symmetrical supercapacitors (ASSCs) are offering the safest and cost-effective solution to fulfill the ever-increasing demand for high-performance energy storage devices. However, the narrow operational voltage window in basic electrolytes is significantly limits their practical applications. Herein, we demonstrate a high-voltage ASSCs in a basic electrolyte by combining the binder-free highly Faradic-type cobalt and highly capacitive-type molybdenum oxides with rich oxidation/reduction states. The electrochemical performance of mesoporous cobalt-molybdenum oxide supported on carbon cloth (Co-Mo-O@CC) are first optimized in three electrode-system and it reveals high-capacitance of 1437.5 F g(-1) (862.5 C g(-1)) at 1.5 A g(-1) with outstanding rate-capability (81.19%) and cycling stability (95%) over 8000 cycles. Moreover, the fabricated ASSC based on the Co-Mo-O@CC electrodes (CMO vertical bar vertical bar CMO-ASSC) is delivered admirable performance by exhibiting the high-capacitance of 180.5 F g(-1) (2.63 F cm(-2)) at 1.0 A g(-1) with good rate capability of 72.34% at high current density of 8 A g(-1) as well as decent capacitance retention of 91.80% after 15000 cycles. The CMO vertical bar vertical bar CMO-ASSC displayed a high energy density of 40.77 Wh kg(-1) at a high-power density of 894.24 W kg(-1) (based on the mass of active materials), which is the best value among ASSCs reported previously. Furthermore, the two CMO vertical bar vertical bar CMO-ASSC coupled in series can charge up to 2.4 V and power two red color light-emitting-diodes (LEDs), demonstrating its practical applications as energy storage devices. Thus, this work paves a novel way to develop high-voltage ASSCs with large energy density and super long life energy storage devices. (C) 2019 Elsevier Ltd. All rights reserved.