联系我们
意见反馈

关注公众号

获得最新科研资讯

Chemical Kinetics in Shock and Detonation Wave

简介 Prof. Remy Mevel's Group

分享到

Determination of explosion combustion parameters of H2/O2/N2 mixtures

2012
会议 Nineth International Symposium on Hazard, Prevention, and Mitigation of Industrial Explosions
The aim of the present work is to assess the risk of explosion of {H2 / O2 / N2} mixtures through the characterization of their fundamental combustion properties: (i) laminar flame speed (SL°), maximum combustion pressure (PMAX) and pressure rise (dP/dt)MAX in a spherical vessel ; (ii) detonation speed and cell size using a cylindrical detonation tube. Equilibrium calculations were made to obtain: (i) theoretical maximum pressure (PAICC), (ii) the Theoretical Chapman-Jouguet detonation velocity. Simulated laminar flame speeds using COSILAB have been obtained. A suitable model has been selected in order to determine the activation energy of these mixtures. The proportionality factor between the detonation cell size and the induction length has been derived based on the ZND model and using a detailed kinetic mechanism.